103660-91-9

Upstream product

• 631-67-4 N,N-dimethylthioacetamide 
• 1517-82-4 (-)-(S)-menthyl toluene-p-sulphinate 

Downstream Products

• 103660-94-2 3-Hydroxy-N,N-dimethyl-3-phenyl-2-((R)-toluene-4-sulfinyl)-thiopropionamide 
• 103660-95-3 (R)-3-Hydroxy-N,N-dimethyl-thiobutyramide 
• 103660-95-3 (S)-3-Hydroxy-N,N-dimethyl-thiobutyramide 
• 103660-95-3 3-Hydroxy-N,N-dimethyl-thiobutyramide 
• 103660-93-1 3-Hydroxy-4-methyl-2-((R)-toluene-4-sulfinyl)-pentanethioic acid dimethylamide 
• 103660-97-5 (S)-3-Hydroxy-4-methyl-pentanethioic acid dimethylamide 
• 103660-97-5 (R)-3-hydroxy-N,N,4-trimethylpentanethioamide 
• 103660-92-0 3-Hydroxy-5-methyl-2-((R)-toluene-4-sulfinyl)-hexanethioic acid dimethylamide 

Relevant academic research and scientific papers

ASYMMETRIC SYNTHESIS OF β-HYDROXYTHIOACETAMIDES MEDIATED BY ENANTIOMERICALLY PURE SULPHINYL DERIVATIVES.

Enantiomerically pure p-tolyl sulphinyl-N,N-dimethylthioacetamide (1) was prepared starting from (-)-(S)-menthyl toluene-p-sulphinate.Aldol-type condensation of (1) and subsequent removal of the sulphinyl group open an entry to optically active β-hydroxy thioacetamides in 40-90percent e.e.