Tetrahedron p. 4929 - 4936 (1985)
Update date:2022-07-30
Topics:
Cinquini, Mauro
Manfredi, Amedea
Molinari, Henriette
Restelli, Angelo
Enantiomerically pure p-tolyl sulphinyl-N,N-dimethylthioacetamide (1) was prepared starting from (-)-(S)-menthyl toluene-p-sulphinate.Aldol-type condensation of (1) and subsequent removal of the sulphinyl group open an entry to optically active β-hydroxy thioacetamides in 40-90percent e.e.
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