103698-35-7

Basic information

• Product Name: 2-(1-adamantyl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane
• Synonyms: 2-(1-adamantyl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane
• CAS NO: 103698-35-7
• Molecular Weight: 413.605
• Mol File: 103698-35-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-(1-adamantyl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1-adamantyl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane(103698-35-7)
• EPA Substance Registry System: 2-(1-adamantyl)-1-phenylsulphonyl-1-(pyridine-2-thiyl)ethane(103698-35-7)

Safety Data

• Hazardous Substances Data: 103698-35-7(Hazardous Substances Data)

Upstream product

• 91233-19-1 1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione 
• 69627-08-3 1-(phenylsulfonyl)-1-(trimethylsilyl)ethene 
• 5535-48-8 PVS 

Downstream Products

• 137170-74-2 trans 2-(adamant-1-yl)-1-phenylsulphonyl ethene 
• 126002-57-1 (3r,5r,7r)-1-(2-(phenylsulfonyl)ethyl)adamantane 

Relevant articles and documents

The Invention of Radical Reactions. XXXIII Homologation Reactions of Carboxylic Acids by Radical Chain Chemistry

Various carbon radicals can be generated from carboxylic acids via the corresponding Barton esters.These radicals can be used for the synthesis of longer chain homologues of the original acids.

RADICAL ADDITION TO VINYL SULPHONES AND VINYL PHOSPHONIUM SALTS

Alkyl radicals, derived from decarboxylation of carboxylic acids, add readily to phenyl vinyl sulphone and vinyl phosphonium bromide.The adducts may be further converted into a variety of useful synthetic intermediates.