126002-57-1

Basic information

• Product Name: (3r,5r,7r)-1-(2-(phenylsulfonyl)ethyl)adamantane
• Synonyms: (3r,5r,7r)-1-(2-(phenylsulfonyl)ethyl)adamantane
• CAS NO: 126002-57-1
• Molecular Weight: 304.453
• Mol File: 126002-57-1.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: (3r,5r,7r)-1-(2-(phenylsulfonyl)ethyl)adamantane(CAS DataBase Reference)
• NIST Chemistry Reference: (3r,5r,7r)-1-(2-(phenylsulfonyl)ethyl)adamantane(126002-57-1)
• EPA Substance Registry System: (3r,5r,7r)-1-(2-(phenylsulfonyl)ethyl)adamantane(126002-57-1)

Safety Data

• Hazardous Substances Data: 126002-57-1(Hazardous Substances Data)

Upstream product

• 5535-48-8 PVS 
• 80859-83-2 1-benzene 
• 152954-27-3 -1-naphthalene 
• 152954-31-9 C₃₀H₃₅IO₈ 
• 161564-33-6 1--4-methoxybenzene 
• 161564-34-7 1--4-methylbenzene 
• 161564-35-8 1--4-chlorobenzene 
• 161564-36-9 1--4-nitrobenzene 
• 79057-62-8 O-(adamantan-1-yl) S-methyl carbonodithioate 
• 768-94-5 1-Adamantanamine 
• 118334-83-1 1,3-dioxoisoindolin-2-yl (3r,5r,7r)-adamantane-1- carboxylate 
• 281-23-2 adamantane 
• 828-51-3 1-Adamantanecarboxylic acid 
• 37994-84-6 Chloro-oxo-acetic acid adamantan-1-yl ester 

Relevant articles and documents

1-Ethylpiperidinium Hypophosphite: A Practical Mediator for Radical Carbon-Carbon Bond Formation

1-Ethylpiperidinium hypophosphite could be used efficiently as radical chain carrier in the intermolecular carbon-carbon bond formation without using excess of alkenes under mild reaction conditions.

Decarboxylative Giese-Type Reaction of Carboxylic Acids Promoted by Visible Light: A Sustainable and Photoredox-Neutral Protocol

We describe herein a transition-metal-free method for the decarboxylative generation of radicals from carboxylic acids and their 1,4-addition to Michael acceptors. The Fukuzumi catalyst (9-mesitylene-10-methylacridinium perchlorate, [Acr-Mes]ClO4) enabled this transformation under visible-light irradiation at room temperature with CO2 as the only byproduct. The scope and limitations of this protocol were examined by using a range of Michael acceptors (15 examples) and carboxylic acids (18 examples). The use of 3-hydroxypivalic acid in this protocol allowed the straightforward formation of a diastereomerically pure δ-lactone. Moreover, when a homoallylic acid was used, a radical cascade reaction took place with the formation of three C–C bonds.

Catalyst-Controlled C-H Functionalization of Adamantanes Using Selective H-Atom Transfer

A method for the direct functionalization of diamondoids has been developed using photoredox and H atom transfer catalysis. This C-H alkylation reaction has excellent chemoselectivity for the strong 3° C-H bonds of adamantanes in polyfunctional molecules.

Catalyst-Free Decarboxylation of Carboxylic Acids and Deoxygenation of Alcohols by Electro-Induced Radical Formation

Electro-induced reduction of redox active esters and N-phthalimidoyl oxalates derived from naturally abundant carboxylic acids and alcohols provides a sustainable and inexpensive approach to radical formation via undivided electrochemical cells. The resulting radicals are trapped by an electron-poor olefin or hydrogen atom source to furnish the Giese reaction or reductive decarboxylation products, respectively. A broad range of carboxylic acid (1°, 2°, and 3°) and alcohol (2° and 3°) derivatives are applicable in this catalyst-free reaction, which tolerated a diverse range of functional groups. This method features simple operation, is a sustainable platform, and has broad application.