1037510-10-3

Upstream product

• 158716-07-5 phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside 
• 173019-83-5 1-(3-bromoprop-1-yn-1-yl)-4-(trifluoromethyl)benzene 

Downstream Products

• 1039169-36-2 methyl 2,3,4-tri-O-benzyl-6-O-[4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-β-D-mannopyranosyl]-α-D-glucopyranoside 
• 1039169-34-0 methyl 2,3,6-tri-O-benzyl-4-O-[4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-β-D-mannopyranosyl]-α-D-glucopyranoside 
• 1039169-32-8 1-adamantanyl 4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-β-D-mannopyranoside 
• 1039169-39-5 1,6-anhydro-4-O-[4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-β-D-mannopyranosyl]-2,3-O-isopropylidene-β-D-mannopyranose 
• 1039169-45-3 methyl 2-azido-3,6-di-O-benzyl-4-O-[4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-β-D-mannopyranosyl]-α-D-glucopyranoside 
• 1039169-38-4 methyl 4-O-[4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-β-D-mannopyranosyl]-2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 1039169-43-1 6-O-[4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-β-D-mannopyranosyl]-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 
• 1039169-41-9 3-O-[4,6-O-benzylidene-2-O-[3-(4-trifluoromethylphenyl)-prop-2-ynyl]-3-O-benzyl-β-D-mannopyranosyl]-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 1268373-62-1 C₄₇H₅₉F₃O₇ 
• 1268373-54-1 C₅₃H₆₆F₃NO₉ 

Relevant academic research and scientific papers

Application of the 4-trifluoromethylbenzenepropargyl ether group as an unhindered, electron deficient protecting group for stereoselective glycosylation

(Chemical Equation Presented) 4-Trifluoromethylbenzenepropargyl ethers are stable and sterically minimal alcohol protecting groups that are readily cleaved in a single step by exposure to lithium naphthalenide. In conjunction with the 4,6-O-benzylidene protecting group, glycosylation reactions of 2-O-(4-trifluoromethylbenzenepropargyl)-protected mannosyl donors are extremely β-selective.