103826-27-3Relevant academic research and scientific papers
METALLIC BISMUTH MEDIATED ALLYLATION OF ALDEHYDES TO HOMOALLYLIC ALCOHOLS
Wada, Makoto,Akiba, Kin-ya
, p. 4211 - 4212 (1985)
In the presence of metallic bismuth, allyl halides were found to react with aldehydes under mild conditions to give the corresponding homoallylic alcohols in good yields.
A Grignard-Type Addition of Allyl Unit to Aldehydes by Using Bismuth and Bismuth Salt
Wada, Makoto,Ohki, Hidenori,Akiba, Kin-ya
, p. 1738 - 1747 (1990)
In the presence of metallic bismuth, bismuth(III) chloride-metallic zinc, or bismuth(III) chloride-metallic iron, allylic halides have been found to react with aldehydes under mild conditions to give the corresponding homoallylic alcohols in high yields with high chemo-, regio-, and stereoselectivity.Allylic halides have been also found to react with aldehydes at room temperature in tetrahydrofuran-water by using bismuth(III) chloride-metallic aluminium to afford the expected homoallylic alcohols in high yields.
