1038436-37-1

Basic information

• Product Name: (R)-(-)-1-[2-(benzyloxy)-5-bromophenoxy]-3,3-dimethylbutan-2-ol
• Synonyms: (R)-(-)-1-[2-(benzyloxy)-5-bromophenoxy]-3,3-dimethylbutan-2-ol
• CAS NO: 1038436-37-1
• Molecular Weight: 379.294
• Mol File: 1038436-37-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-(-)-1-[2-(benzyloxy)-5-bromophenoxy]-3,3-dimethylbutan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(-)-1-[2-(benzyloxy)-5-bromophenoxy]-3,3-dimethylbutan-2-ol(1038436-37-1)
• EPA Substance Registry System: (R)-(-)-1-[2-(benzyloxy)-5-bromophenoxy]-3,3-dimethylbutan-2-ol(1038436-37-1)

Safety Data

• Hazardous Substances Data: 1038436-37-1(Hazardous Substances Data)

Upstream product

• 2245-30-9 (R)-tert-butyloxirane 
• 153241-03-3 2-(benzyloxy)-5-bromophenol 

Downstream Products

• 943226-24-2 (+)-2-[(R)-2-hydroxy-3,3-dimethylbutoxy]-4-bromophenol 

Relevant articles and documents

Highly diastereoselective synthesis of orthoquinone monoketals through λ13-iodane-mediated oxidative dearomatization of phenols

(Chemical Equation Presented) Versatile chiral substrates for asymmetric synthesis are formed through the spiroketalization of phenols with a chiral substituted ethanol unit O-tethered to the ortho position upon treatment with PhI-(OAc)2 (see example; TFE = 2,2,2-tri-fluoroethanol). Intermediates with a six-membered iodine(III)-containing ring (the natural localized molecular orbitals associated with the I-C6 bond are shown) undergo ligand coupling to give the spiroketals.