10386-81-9Relevant articles and documents
Reduction of 2-alkyl-2-carbomethoxy-cyclopentanone derivatives with sodium borohydride. Part 2. The elucidation of the diastereoselective control
Teixeira, Lis H. P.,Barreiro, Eliezer J.,Fraga, Carlos A. M.
, p. 3241 - 3257 (1997)
The synthesis and reduction of four new 2-substituted β-keto-ester derivatives (6-9) employing inexpensive sodium borohydride, were achieved to evaluate the diastereoselectivity of the reduction process of 2-allyl-2- carbomethoxy cyclopentanone derivative
γ-Lactone Synthesis via Palladium(II)-Catalyzed Lactonization of Unactivated Methylene C(sp3)-H Bonds
Liu, Bin,Shi, Bing-Feng
supporting information, p. 2396 - 2400 (2016/09/28)
A palladium(II)-catalyzed intramolecular lactonization of unactivated methylene C(sp3)-H bonds using PIP bidentate auxiliary is described. This method provides an efficient and concise pathway to synthesize functionalized γ-lactones.
Synthesis of enantiopure 1-r-alkyl-2-c,5-t-diphenylphospholanes and phospholanium salts through direct alkylation of phospholane
Dobrota, Cristian,Duraud, Amelie,Toffano, Martial,Fiaud, Jean-Claude
body text, p. 2439 - 2445 (2009/04/10)
Chiral enantiopure 1-alkyl-2,5-diphenylphospholanium salts were obtained in one step through alkylation of phospholane with alkyl triflates. The resulting air-stable phosphonium salts are electron-rich trialkylphosphane precursor ligands for transition metals, and they offer a convenient route toward chiral quaternary phosphonium salts as phase-transfer agents. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
