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103867-69-2

(E)-2-Phenyl-6-(toluene-4-sulfinyl)-hex-5-en-3-ol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 103867-69-2 Structure

  • Basic information

    1. Product Name: (E)-2-Phenyl-6-(toluene-4-sulfinyl)-hex-5-en-3-ol
    2. Synonyms:
    3. CAS NO:103867-69-2
    4. Molecular Formula:
    5. Molecular Weight: 314.448
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 103867-69-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (E)-2-Phenyl-6-(toluene-4-sulfinyl)-hex-5-en-3-ol(CAS DataBase Reference)
    10. NIST Chemistry Reference: (E)-2-Phenyl-6-(toluene-4-sulfinyl)-hex-5-en-3-ol(103867-69-2)
    11. EPA Substance Registry System: (E)-2-Phenyl-6-(toluene-4-sulfinyl)-hex-5-en-3-ol(103867-69-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 103867-69-2(Hazardous Substances Data)

103867-69-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 103867-69-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,3,8,6 and 7 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 103867-69:
(8*1)+(7*0)+(6*3)+(5*8)+(4*6)+(3*7)+(2*6)+(1*9)=132
132 % 10 = 2
So 103867-69-2 is a valid CAS Registry Number.

103867-69-2Relevant articles and documents

Cram-selective Addition of α-Allyl Sulphinyl Anion to Chiral Aldehydes: Synthesis of (E)-1,4-Dihydroxyalk-2-enes

Annunziata, Rita,Cinquini, Mauro,Cozzi, Franco,Raimondi, Laura

, p. 366 - 367 (1986)

The stereoselective introduction of an allylic alcohol function into chiral aldehydes is readily achieved by sequential condensation of aldehydes with an allylic sulphinyl anion and thiophile-promoted desulphurization of the resulting α-substituted allylic sulphoxides.

STEREOSELECTIVE SYNTHESIS OF (E)-2-ALKENE-1,4-DIOLS VIA METALLATED ALLYLIC SULPHOXIDES

Annunziata, Rita,Cinquino, Mauro,Cozzi, Franco,Raimondi, Laura,Stefanelli, Stefania

, p. 5443 - 5450 (2007/10/02)

Reaction of allyl sulphinyl anion with chiral α-methylaldehydes affords α- or γ-adducts in highly regiocontrolled fashion, depending on reaction conditions.From the α-adducts syn (E)-2-alkene-1,4-diols are obtained as major (d.r. 2:1 28:1) products by thiophile promoted desulphurization.

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