110210-79-2Relevant articles and documents
STEREOSELECTIVE SYNTHESIS OF (E)-2-ALKENE-1,4-DIOLS VIA METALLATED ALLYLIC SULPHOXIDES
Annunziata, Rita,Cinquino, Mauro,Cozzi, Franco,Raimondi, Laura,Stefanelli, Stefania
, p. 5443 - 5450 (2007/10/02)
Reaction of allyl sulphinyl anion with chiral α-methylaldehydes affords α- or γ-adducts in highly regiocontrolled fashion, depending on reaction conditions.From the α-adducts syn (E)-2-alkene-1,4-diols are obtained as major (d.r. 2:1 28:1) products by thiophile promoted desulphurization.