1039136-70-3Relevant academic research and scientific papers
Selective formal transesterification of fluorinated 2-(trimethylsilyl)ethyl α-imino esters mediated by TBAF
Fustero, Santos,Sanchez-Rosello, Maria,Rodrigo, Vanessa,Garcia, Amador,Catalan, Silvia,Del Pozo, Carlos
, p. 5617 - 5620 (2008/12/21)
(Chemical Equation Presented) The scope of the transesterification reaction between β-fluorinated α-imino esters and various electrophiles in the presence of TBAF as fluorine source is described. The reaction is highly selective for alkyl iodides, bromide
Asymmetric synthesis of new β,β-difluorinated cyclic quaternary α-amino acid derivatives
Fustero, Santos,Sanchez-Rosello, Maria,Rodrigo, Vanessa,Del Pozo, Carlos,Sanz-Cervera, Juan F.,Simon, Antonio
, p. 4129 - 4132 (2007/10/03)
The synthesis of new β,β-difluorinated cyclic quaternary α-amino acid derivatives 1 in which a ring-closing metathesis reaction (RCM) constitutes the key step is described. The approach employs imidoyl chlorides 3 as fluorinated building blocks, and the o
