103929-85-7

Basic information

• Product Name: 1-(ChloroMethyl)-3,5-bis[[(1,1-diMethylethyl)diMethylsilyl]oxy]benzene
• Synonyms: 1-(ChloroMethyl)-3,5-bis[[(1,1-diMethylethyl)diMethylsilyl]oxy]benzene
• CAS NO: 103929-85-7
• Molecular Formula: C₁₉H₃₅ClO₂Si₂
• Molecular Weight: 387.104
• Product Categories: Aromatics, Pharmaceuticals, Intermediates & Fine Chemicals
• Mol File: 103929-85-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• Solubility: Diethyl Ether, Hexanes
• CAS DataBase Reference: 1-(ChloroMethyl)-3,5-bis[[(1,1-diMethylethyl)diMethylsilyl]oxy]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(ChloroMethyl)-3,5-bis[[(1,1-diMethylethyl)diMethylsilyl]oxy]benzene(103929-85-7)
• EPA Substance Registry System: 1-(ChloroMethyl)-3,5-bis[[(1,1-diMethylethyl)diMethylsilyl]oxy]benzene(103929-85-7)

Safety Data

• Hazardous Substances Data: 103929-85-7(Hazardous Substances Data)

Usage

Chemical Properties

1-(ChloroMethyl)-3,5-bis[[(1,1-diMethylethyl)diMethylsilyl]oxy]benzene is White Clear Oil

Uses

1-(ChloroMethyl)-3,5-bis[[(1,1-diMethylethyl)diMethylsilyl]oxy]benzene is a reactant used in the synthesis of natural polyhydroxystilbenes.

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 103929-83-5 methyl 3,5-bis(tert-butyldimethylsilyloxy)benzoate 
• 2150-44-9 1-carbomethoxy-3,5-dihydroxybenzene 
• 103929-84-6 [3,5-di(tert-butyldimethylsilanyloxy)phenyl]methanol 

Downstream Products

• 205523-92-8 1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-((Z)-tridec-8-enyl)-benzene 
• 1018449-53-0 3',4'-bis(tert-butyldimethylsiloxy)-3,5-dihydroxystilbene 
• 107192-05-2 1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-((E)-styryl)-benzene 
• 107030-46-6 1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-((Z)-styryl)-benzene 
• 106325-83-1 C₃₈H₆₈O₄Si₄ 
• 22139-77-1 pinosylvin 
• 205523-89-3 1,3-Bis-(tert-butyl-dimethyl-silanyloxy)-5-[(E)-8-(1-ethoxy-ethoxy)-oct-1-enyl]-benzene 
• 205523-91-7 8-[3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-octanal 
• 205523-90-6 8-[3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-phenyl]-octan-1-ol 
• 62897-10-3 ardisinol II 
• 676596-85-3 (E)-1-(3,5-bis-{[tert-butyl(dimethyl)silyl]oxy}phenyl)-2-(4-{[tert-butyl(dimethyl)silyl]oxy}phenyl)ethene 
• 501-36-0 (E)-5-[2-4-(hydroxyphenyl)ethenyl]-1,3-benzenediol 
• 869011-52-9 diethyl [3,5-bis(tert-butyldimethylsilyloxy)phenyl]methylphosphonate 
• 103929-86-8 3,5-di-t-butyldimethylsilyloxybenziltriphenylphosphonium chloride 

Relevant articles and documents

Biomimic transformation of resveratrol

Resveratrol was treated with several kinds of peroxidases and inorganic reagents so as to prepare ε-viniferin. Among several inorganic reagents, which were investigated in this study, thallium(III) nitrate in methanol gave (±)-ε-viniferin in the yield of 68%. On the other hand, peroxidases did not lead to ε-viniferin, but some stilbenedimers such as pallidol, resveratrol trans-dehydrodimer, and leachianol F were obtained.

SYNTHESIS OF NATURAL POLYHYDROXYSTILBENES

A synthesis of several natural polyhydroxystilbenes is described.