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103934-13-0

anti-4-methyl-1-phenyl-6-(trimethylsilyl)-5-hexyn-3-ol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 103934-13-0 Structure

  • Basic information

    1. Product Name: anti-4-methyl-1-phenyl-6-(trimethylsilyl)-5-hexyn-3-ol
    2. Synonyms:
    3. CAS NO:103934-13-0
    4. Molecular Formula:
    5. Molecular Weight: 260.451
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 103934-13-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: anti-4-methyl-1-phenyl-6-(trimethylsilyl)-5-hexyn-3-ol(CAS DataBase Reference)
    10. NIST Chemistry Reference: anti-4-methyl-1-phenyl-6-(trimethylsilyl)-5-hexyn-3-ol(103934-13-0)
    11. EPA Substance Registry System: anti-4-methyl-1-phenyl-6-(trimethylsilyl)-5-hexyn-3-ol(103934-13-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 103934-13-0(Hazardous Substances Data)

103934-13-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 103934-13-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,3,9,3 and 4 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 103934-13:
(8*1)+(7*0)+(6*3)+(5*9)+(4*3)+(3*4)+(2*1)+(1*3)=100
100 % 10 = 0
So 103934-13-0 is a valid CAS Registry Number.

103934-13-0Downstream Products

103934-13-0Relevant articles and documents

Preparation of syn -Tertiary homoallylic alcohols utilizing allenyltitanocenes generated by reductive titanation of γ- Trimethylsilylpropargylic carbonates

Yatsumonji, Yasutaka,Sugita, Takenori,Tsubouchi, Akira,Takeda, Takeshi

supporting information; experimental part, p. 1968 - 1971 (2010/07/06)

Figure presented syn-Tertiary homoallylic alcohols were obtained by the reaction of α-silylallenyltitanocenes generated by the reductive titanation of γ-silylpropargylic carbonates with Cp2Ti[P(OEt) 3]2 with ketones and fo

Scope and Stereochemical Course of the Addition of (Trimethylsilyl)allenes to Ketones and Aldehydes. A Regiocontrolled Synthesis of Homopropargylic Alcohols

Danheiser, Rick L.,Carini, David J.,Kwasigroch, Carrie A.

, p. 3870 - 3878 (2007/10/02)

The reaction of (trimethylsilyl)allenes with aldehydes and ketones in the presence of titanium tetrachloride provides a regiocontrolled route to homopropargylic alcohols of a variety of substitution types.The addition of 1-alkyl-substituted (trimethylsilyl)allenes to carbonyl compounds furnishes the desired acetylenes directly, while reactions involving allenylsilanes 6,7, and 9 initially produce mixtures of acetylenes and (trimethylsilyl)vinyl chloride derivatives.Exposure of these mixtures to the action of potassium fluoride in dimethyl sulfoxide then generates the desired homopropargylic alcohols.The addition of the chiral allenylsilane 9 to achiral aldehydes has been found to proceed with modest (3-4:1) diastereoselectivity to produce mainly syn (erythro) homopropargylic alcohols.

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