1039644-07-9Relevant academic research and scientific papers
Highly regioselective ring-opening of aziridines with arenesulfinates on water: A facile access to β-amino/vinyl sulfones
Chawla, Ruchi,Singh, Atul K.,Yadav, Lal Dhar S.
, p. 1720 - 1724 (2013/03/13)
We have developed a LiBr catalyzed efficient synthesis of β-amino sulfones from readily available aziridines and sodium sulfinates in good to excellent yields. The synthetic potential of β-amino sulfones has also been demonstrated by their facile conversion to the corresponding vinyl sulfones. The use of water as reaction media, atom-economy and isolation of products by simple filtration in the case of solid β-amino sulfones are certain green virtues of the synthetic protocol.
Unexpected transfer of tosyl group of ArCH=NTs-catalyzed by N-heterocyclic carbene
Chen, Dong-Dong,Hou, Xue-Long,Dai, Li-Xin
, p. 5578 - 5581 (2008/12/20)
(Chemical Equation Presented) Reactions of N-tosylimines with aziridines and electron-deficient unsaturated compounds in the presence of catalytic amount of NHC afforded unexpected tosyl group transfer products in good to high yields, which represent a new reaction pattern for imines as well as for catalysis of NHC.
