1039660-92-8

Basic information

• Product Name: (2R,4R)-2,4-diphenyl-3-tosyloxazolidine
• Synonyms: (2R,4R)-2,4-diphenyl-3-tosyloxazolidine
• CAS NO: 1039660-92-8
• Molecular Weight: 379.48
• Mol File: 1039660-92-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2R,4R)-2,4-diphenyl-3-tosyloxazolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,4R)-2,4-diphenyl-3-tosyloxazolidine(1039660-92-8)
• EPA Substance Registry System: (2R,4R)-2,4-diphenyl-3-tosyloxazolidine(1039660-92-8)

Safety Data

• Hazardous Substances Data: 1039660-92-8(Hazardous Substances Data)

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 118917-59-2 (R)-N-(2-hydroxy-1-phenylethyl)-4-methyl-S-methylenebenzenesulfinamide 
• 63160-12-3 2-[(4-methylphenyl)sulfonyl]-3-phenyl-oxaziridine 
• 100-42-5 styrene 

Relevant articles and documents

Organocatalytic oxyamination of azlactones: Kinetic resolution of oxaziridines and asymmetric synthesis of oxazolin-4-ones

The first example of oxyamination of azlactones with oxaziridines was realized using a chiral bisguanidinium salt. Efficient catalytic asymmetric oxyamination and kinetic resolution of oxaziridines occurred simultaneously. Various chiral oxazolin-4-one derivatives with potential biological activity were obtained (up to 92% ee). Meanwhile, a series of optically pure oxaziridines were recovered with up to 99% ee and successfully used in the asymmetric oxyamination of 3-methyl-1H-indole and styrene. The triple stereodifferentiation process was also studied via control experiments.