103971-60-4Relevant articles and documents
Highly regioselective palladium-catalyzed double hydroselenation of terminal alkynes with benzeneselenol in the presence of acetic acid
Ikeda, Takuma,Tamai, Taichi,Daitou, Masayuki,Minamida, Yoshiaki,Mitamura, Takenori,Kusano, Hiroki,Nomoto, Akihiro,Ogawa, Akiya
, p. 1383 - 1385 (2013/11/19)
Palladium diacetate (Pd(OAc)2), in the presence of acetic acid, is found to exhibit excellent catalytic activity for the double hydroselenation of terminal alkynes with benzeneselenol to yield the corresponding diselenoketals regioselectively.
The first example of transitionmetal-catalyzed hydroselenation of acetylenes
Kuniyasu, Hitoshi,Ogawa, Akiya,Sato, Ken-Ichiro,Ryu, Iihyong,Sonoda, Noboru
, p. 5525 - 5528 (2007/10/02)
A variety of transition metal complexes catalyzed the regioselective hydroselenation of acetylenes. In particular, the palladium acetate-catalyzed reaction afforded the Markovnikov adducts with high selectivity.