63831-77-6Relevant articles and documents
Highly regioselective hydroselenation and double-bond isomerization of terminal alkynes with benzeneselenol catalyzed by bis(triphenylphosphine) palladium(II) dichloride
Ozaki, Toshiya,Kotani, Mao,Kusano, Hiroki,Nomoto, Akihiro,Ogawa, Akiya
experimental part, p. 450 - 455 (2011/02/17)
Bis(triphenylphosphine)palladium(II) dichloride (PdCl2(PPh 3)2) catalyzes regioselective addition of benzeneselenol to terminal alkynes and the subsequent double-bond isomerization to afford the corresponding internal alkenyl selenides in good yields.
The Pt-Catalyzed Carboselenation of Alkynes by Selenoesters
Hirai, Takayoshi,Kuniyasu, Hitoshi,Kato, Tomohiro,Kurata, Yumi,Kambe, Nobuaki
, p. 3871 - 3873 (2007/10/03)
(Matrix presented) The Pt-catalyzed carboselenation of terminal alkynes with selenoesters provided vinylselenides regio- and stereoselectively in moderate yields.
The first example of transitionmetal-catalyzed hydroselenation of acetylenes
Kuniyasu, Hitoshi,Ogawa, Akiya,Sato, Ken-Ichiro,Ryu, Iihyong,Sonoda, Noboru
, p. 5525 - 5528 (2007/10/02)
A variety of transition metal complexes catalyzed the regioselective hydroselenation of acetylenes. In particular, the palladium acetate-catalyzed reaction afforded the Markovnikov adducts with high selectivity.