103979-40-4Relevant academic research and scientific papers
Bis(phenylsulfonyl)methane mediated synthesis of olefins: Via a halogen elimination and double bond migration
Hu, Yanwei,Jiang, Jing,Hu, Ying,Cai, Xin,Wang, Liudi,Chen, Shaohua,Zhang, Shilei,Zhang, Yinan
, p. 2619 - 2622 (2018/04/27)
An effective dehydrochlorination of bis(phenylsulfonyl)alkane to prepare alkene building blocks is developed. The elimination together with double bond migration results in a variety of β,γ-unsaturated bis(phenylsulfonyl)olefins in good yields with only E geometry. The following chemical diversification represents an easy and straightforward access to a series of alkene building blocks.
Elimination and Addition Reactions. Part 40. The Insignificant Effect of Strain in Higher Order Eliminations in 1,1-bis(phenylsulphonyl) Carbanions with ω-Leaving Groups
Benedetti, Fabio,Stirling, Charles J.M.
, p. 605 - 612 (2007/10/02)
Rates of cyclisation of 1,1-bis(phenylsulphonyl) carbanions bearing distal leaving groups have been determined.The response of the system to solvent effects and to leaving group is similar to that in intramolecular nucleophilic substitution.The system is
