103980-94-5

Basic information

• Product Name: 1-phenyl-1-(trifluorosilyl)butane
• CAS NO: 103980-94-5
• Molecular Weight: 218.294
• Mol File: 103980-94-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-phenyl-1-(trifluorosilyl)butane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-1-(trifluorosilyl)butane(103980-94-5)
• EPA Substance Registry System: 1-phenyl-1-(trifluorosilyl)butane(103980-94-5)

Safety Data

• Hazardous Substances Data: 103980-94-5(Hazardous Substances Data)

Upstream product

• 1560-09-4 (Z)-but-1-en-1-ylbenzene 
• 104089-93-2 1-phenyl-1-(trichlorosilyl)butane 

Relevant articles and documents

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. 3. Preparation of Optically Active Allylsilanes by Palladium-Catalyzed Asymmetric Grignard Cross-Coupling

Asymmetric cross-coupling of the - or -Grignard reagent with alkenyl bromides in the presence of a chiral ferrocenylphosphine-palladium complex, dichloroethylamine>palladium(II) (PdCl2), as a catalyst, gave optically active allylsilanes which contain an asymmetric carbon atom directly bonded to the silicon atom, e.g., (R)-3-phenyl-3-(trimethylsilyl)propene (3a) (95percent ee), (R,E)-1-phenyl-1-(trimethylsilyl)-2-butene (3b) (85percent ee), (R,Z)-3b (24percent ee), (R,E)-1,3-diphenyl-3- (trimethylsilyl)propene (3c) (95percent ee), (S,E)-1-phenyl-3-(trimethylsilyl)-1-butene (14c) (71percent ee), (S,Z)-14c (59percent ee), (S,E)-1-phenyl-3-(triethylsilyl)-1-butene (16c) (93percent ee), (S,E)-3-(triethylsilyl)-2-pentene (16b) (85percent ee), (S,E,E)-2-(dimethylphenylsilyl)-3,5-heptadiene (15d) (45percent ee), and 1-cyclopentene (21) (37percent ee).The configuration and enantiomeric purity of the allylsilanes were determined with the aid of stereoselective oxidative cleavage of the carbon-silicon bond in optically active alkylsilanes.