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104089-93-2

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104089-93-2 Usage

General Description

1-PHENYL-1-TRICHLOROSILYLBUTANE is a chemical compound with the molecular formula C10H15Cl3Si. It is a member of the organosilicons group and is used as a building block in organic synthesis. The compound contains a phenyl group attached to a trichlorosilyl group, which is connected to a butane chain. Its ability to easily undergo substitution reactions makes it useful in the creation of various organic compounds. It is also known for its water-repellent properties and is used in the production of water-resistant coatings and sealants. Additionally, this compound is utilized in the development of materials for electronic and optoelectronic devices. Despite its potential uses, its reactivity and potential for harm in its pure form make handling and storage precautions necessary.

Check Digit Verification of cas no

The CAS Registry Mumber 104089-93-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,4,0,8 and 9 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 104089-93:
(8*1)+(7*0)+(6*4)+(5*0)+(4*8)+(3*9)+(2*9)+(1*3)=112
112 % 10 = 2
So 104089-93-2 is a valid CAS Registry Number.

104089-93-2Upstream product

104089-93-2Relevant articles and documents

Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine-Transition-Metal Complexes. 3. Preparation of Optically Active Allylsilanes by Palladium-Catalyzed Asymmetric Grignard Cross-Coupling

Hayashi, Tamio,Konishi, Mitsuo,Okamoto, Yasuo,Kabeta, Keiji,Kumada, Makoto

, p. 3772 - 3781 (2007/10/02)

Asymmetric cross-coupling of the - or -Grignard reagent with alkenyl bromides in the presence of a chiral ferrocenylphosphine-palladium complex, dichloroethylamine>palladium(II) (PdCl2), as a catalyst, gave optically active allylsilanes which contain an asymmetric carbon atom directly bonded to the silicon atom, e.g., (R)-3-phenyl-3-(trimethylsilyl)propene (3a) (95percent ee), (R,E)-1-phenyl-1-(trimethylsilyl)-2-butene (3b) (85percent ee), (R,Z)-3b (24percent ee), (R,E)-1,3-diphenyl-3- (trimethylsilyl)propene (3c) (95percent ee), (S,E)-1-phenyl-3-(trimethylsilyl)-1-butene (14c) (71percent ee), (S,Z)-14c (59percent ee), (S,E)-1-phenyl-3-(triethylsilyl)-1-butene (16c) (93percent ee), (S,E)-3-(triethylsilyl)-2-pentene (16b) (85percent ee), (S,E,E)-2-(dimethylphenylsilyl)-3,5-heptadiene (15d) (45percent ee), and 1-cyclopentene (21) (37percent ee).The configuration and enantiomeric purity of the allylsilanes were determined with the aid of stereoselective oxidative cleavage of the carbon-silicon bond in optically active alkylsilanes.

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