104017-07-4

Upstream product

• 1054628-06-6 (2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-tetrahydro-pyran-2-carbonyl chloride 
• 108-95-2 phenol 
• 108164-50-7 Methyl 2,3-di-O-benzyl-4-deoxy-α-D-xylo-hexopyranoside 
• 130799-00-7 methyl 2,3-di-O-benzyl-4-deoxy-α-D-glucopyranosiduronic acid 

Downstream Products

• 104017-09-6 [(2S,4R,5R,6R)-2-Benzenesulfonyl-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-((4S,5R,6S)-4,5-bis-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-methanone 
• 104017-11-0 ((2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-[(2R,4R,5R,6R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2-hydroxy-tetrahydro-pyran-2-yl]-methanone 
• 104017-10-9 ((2S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-[(2S,4R,5R,6R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-methanone 

Relevant academic research and scientific papers

D-GLYCOPYRANOSYL PHENYLSULPHONES: ACYLATION OF THEIR LITHIATED ANIONS AND REDUCTIVE DESULFONYLATION OF THE RESULTING ACYLATED SULFONES. A SYNTHESIS OF α-D-GLYCOSIDES

The lithiated anion of 3,4,6-tri-O-t-butyldimethylsilyl-2-deoxy-α,β-D-glucopyranosyl phenylsulfone reacts with dimethylcarbonate and various phenyl esters to give stable acylated products.Subsequent reductive lithiation leads to enolates which ungergo kin