104017-13-2

Upstream product

• 121702-69-0 (((2R,3S,4R)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diyl)bis(oxy))bis(tert-butyldimethylsilane) 
• 108-98-5 thiophenol 
• 2873-29-2 D-glucal triacetate 
• 151767-37-2 thiophenyl 2-deoxy-3,4,6-tri-O-acetyl-D-glucopyranoside 
• 88580-20-5 3,4,6-tri-O-acetyl-2-deoxy-α-D-arabino-hexopyranosyl chloride 
• 105026-35-5 (2R,3S,4R)-2-Hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3,4-diol 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 21193-75-9 D-galactal 
• 125211-47-4 methyl onate 
• 104016-87-7 phenyl 3,4,6-tri-O-(t-butyldimethylsilyl)-2-deoxy-1-sulphonyl-αβ-D-lyxo-pyranoside 
• 125211-54-3 (4R,5S,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2-phenylsulfanyl-tetrahydro-pyran-2-carboxylic acid 

Downstream Products

• 104016-87-7 phenyl 3,4,6-tri-O-(t-butyldimethylsilyl)-2-deoxy-1-sulphonyl-αβ-D-lyxo-pyranoside 
• 125211-45-2 phenyl 3,4,6-tri-O-(t-butyldimethylsilyl)-2-deoxy-1-sulphonyl-β-D-lyxo-pyranoside 
• 125211-46-3 phenyl 3,4,6-tri-O-(t-butyldimethylsilyl)-2-deoxy-1-sulphonyl-α-D-lyxo-pyranoside 
• 131156-51-9 methyl onate 
• 125211-54-3 (4R,5S,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2-phenylsulfanyl-tetrahydro-pyran-2-carboxylic acid 
• 125211-58-7 (4R,5S,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2-p-tolyloxy-tetrahydro-pyran-2-carboxylic acid 
• 125211-51-0 p-tolyl onate 
• 125211-62-3 p-Tolyl 3,4,6-tri-O-(t-butyldimethylsilyl)-2-deoxy-β-D-galacto-pyranoside 
• 125211-63-4 p-Tolyl 3,4,6-tri-O-(t-butyldimethylsilyl)-2-deoxy-α-D-galacto-pyranoside 
• 125211-47-4 methyl onate 
• 104017-04-1 [(2S,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-phenyl-methanone 
• 104016-91-3 [(2S,4R,5R,6R)-4,5-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-phenyl-methanol 
• 104017-21-2 C₃₀H₅₇⁽²⁾HO₆SSi₃ 
• 104039-25-0 phenylsulfonyl 3,4,6-tri-O-butyldimethylsilyl-2-deoxy-β-D-arabino-hexopyranoside 

Relevant academic research and scientific papers

Diastereoselective Free-radical Reactions. Part 1. Preparation of 2-Deoxy-β-glycosides by Synthesis and Reductive Decarboxylation of 3-Deoxyulosonic Acid Glycosides

A general procedure for the synthesis of 2-deoxy-β-D-glycosides involving the preparation of 3-deoxyulosonic acid glycosides from glycals and their reductive decarboxylation is described.

Preparation and reductive lithiation of 2-deoxy-D-glucopyranosyl phenylsulfones: A highly stereoselective route to C-glycosides

2-Deoxy-D-glucopyranosyl phenylsulfones 3a-c have been synthesized in 75-83% yield from commercial tri-O-acetyl-D-glucal 1. Their reductive desulfonylation by lithium naphthalenide and reaction of the intermediate glycosyl-lithium 5 with aldehydes leads t