104017-21-2

Upstream product

• 2873-29-2 D-glucal triacetate 
• 104017-13-2 (2R,3R,4R)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-phenylsulfanyl-tetrahydro-pyran 
• 151767-37-2 thiophenyl 2-deoxy-3,4,6-tri-O-acetyl-D-glucopyranoside 
• 88580-20-5 3,4,6-tri-O-acetyl-2-deoxy-α-D-arabino-hexopyranosyl chloride 
• 105026-35-5 (2R,3S,4R)-2-Hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3,4-diol 
• 104039-25-0 phenylsulfonyl 3,4,6-tri-O-butyldimethylsilyl-2-deoxy-β-D-arabino-hexopyranoside 
• 108-98-5 thiophenol 

Relevant academic research and scientific papers

Preparation and reductive lithiation of 2-deoxy-D-glucopyranosyl phenylsulfones: A highly stereoselective route to C-glycosides

2-Deoxy-D-glucopyranosyl phenylsulfones 3a-c have been synthesized in 75-83% yield from commercial tri-O-acetyl-D-glucal 1. Their reductive desulfonylation by lithium naphthalenide and reaction of the intermediate glycosyl-lithium 5 with aldehydes leads t