104036-61-5Relevant academic research and scientific papers
Oxidative Cleavage of Mono-, Di-, and Trisubstituted Olefins to Methyl Esters through Ozonolysis in Methanolic NaOH
Marshall, James A.,Garofalo, Albert W.
, p. 3675 - 3680 (2007/10/02)
The ozonolysis of alkenes in methanolic NaOH or NaOMe with CH2Cl2 as cosolvent leads directly to methyl esters.The procedure has been used to prepare various α-, β-, and ω-alkoxy esters, acyloxy esters, and α- and β-N-acyl and N-sulfonyl esters from appropriate unsaturated ethers, esters and amides.Other examples include the formation of dimethyl octanedioate from cyclooctene (75percent yield), dimethyl nonanedioate and methyl nonaoate from methyl oleate (77 and 78percent, respectively), and tetradecanoic acid γ-lactone from 2-methyl-2-hexadecen-6-ol (80percent yield).
RHODIUM CATALYZED REDUCTIVE ESTERIFICATION REACTIONS
Lin, Ivan J. B.,Zahalka, Hayder A.,Alper, Howard
, p. 1759 - 1762 (2007/10/02)
Reductive esterification occurs when unsaturated acids are treated with hydrogen in alcohol using either rhodium trichloride or the dimer of chloro(1,5-hexadiene)rhodium(I) as the catalyst.Saturated acids containing appropriate functional groups are also esterified under the same conditions.
