1040403-46-0Relevant articles and documents
Carbon-nitrogen bond formation involving well-defined aryl-copper(III) complexes
Huffman, Lauren M.,Stahl, Shannon S.
, p. 9196 - 9197 (2008)
Carbon-heteroatom bond formation from copper(III) is commonly invoked as a key step in catalytic reactions, including the century-old Ullmann reactions. Well-defined examples of such reactions have never been observed. Here, we demonstrate that a well-defined Cu(III)-aryl species reacts with a variety nitrogen nucleophiles to undergo facile carbon-nitrogen bond formation. Copyright