104046-98-2Relevant academic research and scientific papers
Mechanistic insight into the cinnamylmetal-thioacetal reaction employing 2-acetoxy-2-phenylacetaldehyde monothioacetal
Sato, Tsuneo,Otera, Junzo
, p. 55 - 62 (1994)
The reaction of 2-acetoxy-2-phenylacetaldehyde monothioacetal with cinnamylsilane and -tin serves as a model system for disclosing the simple diastereoselectivity of unambiguously assigned SN1- and SN2-like reactions between thioacet
DIASTEREOSELECTIVITY, DIASTEREOFACIAL SELECTIVITY AND REGIOSELECTIVITY IN THE REACTIONS OF CYNNAMYL CHLORIDE WITH ALDEHYDES MEDIATED BY TIN AND ALUMINIUM
Coxon, James M.,Eyk, Stephen J. van,Steel, Peter J.
, p. 1029 - 1042 (2007/10/02)
The reaction of cinnamyl chlorie with a series of aryl and alkyl aldehydes mediated by tin and aluminium has been shown to be regioselective and threo diastereoselective.For aldehydes with chirality adjacent to the carbonyl function some diastereofacial s
HIGHLY DIASTEREOSELECTIVE REACTIONS OF (E)-CINNAMYL CHLORIDE WITH ALDEHYDES MEDIATED BY TIN AND ALUMINIUM
Coxon, James M.,Eyk, Stephen J. van,Steel, Peter J.
, p. 6121 - 6124 (2007/10/02)
The reactions of (E)-cinnamyl chloride with aldehydes in H2O:THF:HBr in the presence of tin and aluminium powders proceed with very high stereoselectivity.
