74785-32-3

Basic information

• Product Name: Stannane, tributyl(3-phenyl-2-propenyl)-, (E)-
• Synonyms: tributyl[(E)-cinnamyl]tin;trans-cinnamyltributyltin;(E)-3-phenyl-allyltri-n-butylstannane;Tributyl-trans-cinnamylstannane;(E)-cinnamyl(tributyl)stannane;(E)-cinnamyl(tributyl)tin
• CAS NO: 74785-32-3
• Molecular Formula: C21H36Sn
• Molecular Weight: 407.227
• Mol File: 74785-32-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Stannane, tributyl(3-phenyl-2-propenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane, tributyl(3-phenyl-2-propenyl)-, (E)-(74785-32-3)
• EPA Substance Registry System: Stannane, tributyl(3-phenyl-2-propenyl)-, (E)-(74785-32-3)

Safety Data

• Hazardous Substances Data: 74785-32-3(Hazardous Substances Data)

Upstream product

• 21040-45-9 Cinnamyl acetate 
• 1067-52-3 tributyltin methoxide 
• 1461-22-9 tributyltin chloride 
• 4392-24-9 3-bromo-1-phenyl-1-propenyl bromide 
• 2687-12-9 cinnamyl chloride 

Downstream Products

• 133039-41-5 (E)-1-phenyl-3-(thiophen-3-yl)propene 
• 14906-74-2 2-[(2E)-3-phenyl-2-propen-1-yl]thiophene 
• 54985-33-0 cis-1-(n-Hexyl-1-hydroxy-4-phenyl)-3-buten 
• 54985-37-4 trans-1-(n-Hexyl-1-hydroxy-4-phenyl)-3-buten 
• 40596-18-7 erythro-3-Phenyl-1-decen-4-ol 
• 40596-18-7 (+/-)-anti-3-phenyldec-1-en-4-ol 
• 130826-41-4 (Z)-1-phenyl-3-(tributylstannyl)propene 
• 19752-27-3 1-phenylprop-2-enyl(tributyl)stannane 
• 280570-64-1 ((E)-PhCH=CHCH₂)(COOMe)CC(SnBu₃)(COOMe) 
• 74785-34-5 3-(trans-cinnamyl)-2,5-dimethylbenzoquinone 
• 74785-33-4 5-(trans-cinnamyl)-2,3-dimethylbenzoquinone 

Relevant articles and documents

Practical Stannylation of Allyl Acetates Catalyzed by Nickel with Bu3SnOMe

A practical and scalable nickel-catalyzed allylic stannylation of allyl acetates with Bu3SnOMe is described. A variety of acyclic and cyclic allyl acetates, even with base-sensitive moieties, undergoes the stannylation by using NiBr2/4,4′-di-tert-butylbipyridine (dtbpy)/Mn catalyst system to afford highly functionalized allyl stannanes with excellent regioselectivity and yields. Furthermore, the scope of protocol is also extended by the reaction of propargyl acetates, giving rise to propargyl or allenyl stannanes. Additionally, a unique diastereoselectivity using the nickel catalyst different from the palladium was demonstrated for the stannylation of cyclic allyl acetates. In the reaction, inexpensive and stable nickel complexes, abundant reductant (Mn), and atom-economical stannyl source were used.

Extremely Facile and Stereoselective Preparation of Allylstannanes with Use of Ultrasound

Various allylstannanes are conveniently prepared in quantitative yields by means of ultrasound-promoted Barbier-type reaction from chlorotributylstannane and allyl halides in a stereoselective manner.