104086-70-6Relevant articles and documents
Enzyme-assisted enantioselective synthesis of natural (-)-β-necrodol and its enantiomer
Galano,Audran,Mikolajezyk,Monti
, p. 323 - 326 (2001)
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High diastereoselectivity in Claisen rearrangement in a sterically congested cyclopentane system. Total synthesis of (±)-β-necrodol
Samajdar, Susanta,Ghatak, Anjan,Banerjee, Shyamapada,Ghosh, Subrata
, p. 2011 - 2014 (2001)
Total synthesis of the monoterpene β-necrodol has been accomplished. The key step involves an ortho-ester Claisen rearrangement in a highly sterically congested cyclopentane derivative resulting in a high level of 1,3-trans diastereoselection. A novel photo-induced decarboxylation of the obtained γ,δ-unsaturated acid afforded β-necrodol.
Stereocontrolled total synthesis of (±)-β-necrodol
Samajdar, Susanta,Ghatak, Anjan,Ghosh, Subrata
, p. 4401 - 4402 (2007/10/03)
A total synthesis of racemic β-necrodol is described using an ortho- ester Claisen rearrangement as the key step to dictate a high level of trans- 1,3-diastereoselection on a cyclopentane derivative.