1040926-05-3Relevant academic research and scientific papers
Unprecedented Asymmetric Epoxidation of Isolated Carbon–Carbon Double Bonds by a Chiral Fluorous Fe(III) Salen Complex: Exploiting Fluorophilic Effect for Catalyst Design
Kobayashi, Yuki,Obayashi, Riho,Watanabe, Yuki,Miyazaki, Hiroki,Miyata, Issei,Suzuki, Yuta,Yoshida, Yukihiro,Shioiri, Takayuki,Matsugi, Masato
, p. 2401 - 2408 (2019)
The first asymmetric epoxidation of isolated carbon–carbon double bonds by a chiral salen complex using ubiquitous Fe(III) as a center-metal is described. By simultaneously introducing fluorous tags and tert-butyl groups into the ligand of the salen compl
Direct perfluoroalkylation of non-activated aromatic C-H bonds of phenols
Matsugi, Masato,Hasegawa, Masakazu,Hasebe, Shohei,Takai, Shohei,Suyama, Ryusuke,Wakita, Yusuke,Kudo, Kanako,Imamura, Hiromi,Hayashi, Toshiya,Haga, Seiichi
, p. 4189 - 4191 (2008/09/20)
A simple procedure for the perfluoroalkylation of the aromatic ring of phenols under mildly basic conditions is described. Treatment of a variety of phenols with perfluoroalkyl iodide in the presence of the radical initiator V-70L and Cs2CO3 provided the corresponding perfluoroalkylated products in moderate to good yields. Generally, the reaction proceeded smoothly at room temperature to yield regioselectively perfluoroalkylated products.
