423-39-2Relevant articles and documents
Method for preparing perfluorobutyl iodide
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Paragraph 0022; 0025-0027; 0032; 0035-0037; 0042; 0045; 0046, (2019/05/08)
The invention discloses a method for preparing perfluorobutyl iodide. The method comprises the steps that aluminate ionic liquid is adopted as a solvent and a catalyst, decarboxylation and iodinationof perfluorovaleric acid are conducted under the same condition, and the yield of the perfluorovaleric acid is up to 92% or above. In the process, the step of perfluorovaleric acid alkalization is omitted, conventional liquid alkali is prevented from being used, emission of wastewater and waste salt is reduced, the device cost is reduced, and industrial production is facilitated.
METHOD FOR CONTINUOUS PRODUCTION OF A PERFLUOROALKYL IODIDE TELOMER
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Page 7; 8, (2008/06/13)
The present invention relates to a process for continuously producing a perfluoroalkyl iodide represented by the general formula Rf(CF2CF2)nI, wherein Rf is a C1-6 perfluoroalkyl and n is an integer from 1 to 4, the method comprising continuously supplying a perfluoroalkyl iodide as a telogen represented by the general formula RfI, wherein Rf is as defined above, and tetrafluoroethylene as a taxogen to a tubular reactor packed with a metal catalyst comprising a powdery spherical metal or a sintered metal; and conducting telomerization at a temperature of 60 to 160°C under a pressure of 0.1 to 5 MPa (gauge pressure). According to the present invention, medium-chain perfluoroalkyl iodides can be continuously and efficiently produced with little generation of impurities, such as hydrogen-containing organic compounds and the like.
Kinetics of the photochemical reaction of C, Ind. Eng. Chem. Process Des. 2F5I and C4F9I with C2F4
Linyang, Zhang,Xiaoyu, Zhang,Wcihua, Yang,Xudong, Lou,Fuss
, p. 1158 - 1164 (2007/10/03)
Although the formal insertion of C2F4 into the CI bond of iodides is a chain reaction, we found quantum yields clearly below 1. We show that this is due to an inhibition reaction: the ,Ind. Eng. Chem. Process Des.ery rapid reaction of the radicals with molecular iodine, which accumulates during the reaction in amounts equal to the radical dimers. The corresponding kinetic model quantitati,Ind. Eng. Chem. Process Des.ely describes the quantum yields and product distributions, if we assume for the rate constants kn for the addition of the F(C, Ind. Eng. Chem. Process Des. 2F4)n radicals to C2F4 (in 107 cm3 mol-1 s-1 at 373 and 303 K, respecti,Ind. Eng. Chem. Process Des.ely): k1 = 19 and 3.6, k2 = 8.0 and 1.9, k3 = 1.6 (303 K). ,Ind. Eng. Chem. Process Des.CH ,Ind. Eng. Chem. Process Des.erlagsgesellschaft mbH, 1997.