104108-10-3Relevant academic research and scientific papers
THE FIRST EXAMPLE OF ALDOL REACTIONS BETWEEN TRIMETHYLSILYL ENOL ETHERS AND ALDEHYDES BY THE AID OF RHODIUM COMPLEX
Sato, Susumu,Matsuda, Isamu,Izumi, Yusuke
, p. 5517 - 5520 (1986)
Crossed aldol reaction of trimethylsilyl enol ether with aldehyde is successfully performed with the aid of catalytic amount of rhodium complex, +X- (X = PF6 and ClO4) or Rh4(CO)12, under neutral conditions.
ALDOL CONDENSATIONS CATALYZED BY ORGANOALUMINUM REAGENTS
Naruse, Yuji,Ukai, Junzo,Ikeda, Nobuo,Yamamoto, Hisashi
, p. 1451 - 1452 (2007/10/02)
A new synthetic procedure for the practical synthesis of β-trimethylsiloxyketones from silyl enol ethers and aldehydes has been described which heavily depends on organoaluminum reagent as an effective catalyst.
