THE FIRST EXAMPLE OF ALDOL REACTIONS BETWEEN TRIMETHYLSILYL ENOL ETHERS AND ALDEHYDES BY THE AID OF RHODIUM COMPLEX

DOI: 10.1016/S0040-4039(00)85255-7

Source and publish data:

Tetrahedron Letters p. 5517 - 5520 (1986)

Update date:2022-07-31

Topics:

Authors:

Sato, Susumu

Matsuda, Isamu

Izumi, Yusuke

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)85255-7

Crossed aldol reaction of trimethylsilyl enol ether with aldehyde is successfully performed with the aid of catalytic amount of rhodium complex, <(COD)Rh(DPPB)>⁺X^- (X = PF₆ and ClO₄) or Rh₄(CO)₁₂, under neutral conditions.

Full text of DOI:10.1016/S0040-4039(00)85255-7

Products guided by the article

Product name:2-(Cyclohexyl-trimethylsilanyloxy-methyl)-cyclohexanone

Cas No:104108-10-3

R&D Labs maybe for 104108-10-3

Hubei Vanz Pharm Co.,Ltd

website:http://www.vanzpharm.com/en/index.html

Contact:86-27-84492310

Address:FANHU INDUSTRY PARK
Xi'an yuanfar international trade company

website:https://www.yuanfarchemical.com

Contact:86-029-88745613 ext 828

Address:Floor19th ,B Building, Oak Block,No.36 South Fenghui Road, Dev. Zone of High-Tech Ind.,Xi’an, China
jintan yufan Medicine Raw materials Co.,Ltd.(expird)

Contact:86-519-82808282

Address:6th,Jincheng Huangzhuang
ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei
Feiyang Biotechnology Co., Ltd.

Contact:+86-533-7866339

Address:Qilu Chemistry Park, 200m north of Management Community Building of Park

Relevant to this article

Vanadium-catalyzed asymmetric transcyanation of aliphatic aldehydes with acetone cyanohydrin

Doi:10.1246/cl.2008.502
(2008)
Total Synthesis of Echinocandins. 2. Total Synthesis of Echinocandin D via Efficient Peptide Coupling Reactions

Doi:10.1021/ja00279a065
(1986)
Solvent-free synthesis of 2-amino-3-aryl-5-substituted thiophenes as anti-inflammatory agents using KF-Al2O3 under microwave irradiation

Doi:10.1080/00397910801997843
(2008)
Radical aminomethylation of unactivated alkenes

Doi:10.1021/ol801162m
(2008)
Converting sequences of aromatic amino acid monomers into functional three-dimensional structures: Second-generation helical capsules

Doi:10.1002/anie.200800625
(2008)
Doi:10.1002/hlca.19440270156
(1944)

Article Doi