104115-48-2

Upstream product

• 37865-96-6 2-(2-bromoethyl)-2-methyl-1,3-dioxolane 
• 62240-37-3 2-(2-methyl-1,3-dioxolane-2-yl)ethan-1-amine 
• 104115-44-8 (2-oxocyclopent)acetic acid 
• 104115-46-0 C₁₃H₁₉NO₃ 
• 104115-45-9 N-<2-(2-Methyl-1,3-dioxolan-2-yl)ethyl>-2-oxocyclopentaneacetamide 
• 104115-47-1 C₂₃H₃₁NO₄ 
• 104115-47-1 (7R^*,7aR^*,10aS^*)-(+/-)-Hexahydro-7-<3-(phenylmethoxy)propyl>spiroindolizine-2(1H),2'-<1,3>dioxolan>-6(7H)-one 
• 138489-25-5 (3aR,6aS)-6a-Hydroxy-1-[2-(2-methyl-[1,3]dioxolan-2-yl)-ethyl]-hexahydro-cyclopenta[b]pyrrol-2-one 
• 104115-46-0 (7aR^*,10aS^*)-(+/-)-Hexahydrospiroindolizine-2(1H),2'-<1,3>dioxolan>-6(7H)-one 
• 138489-24-4 (+/-)-(1R^*,5S^*)-1-hydroxy-2-azabicyclo<3.3.0>octan-3-one 
• 138489-23-3 (3aS,6aR)-6a-Chloro-hexahydro-cyclopenta[b]furan-2-one 
• 84764-41-0 2-(2-(2-methyl-1,3-dioxolan-2-yl)ethyl)isoindoline-1,3-dione 
• 107-21-1 ethylene glycol 

Downstream Products

• 104115-49-3 (1''R+S,7R^*,7aR^*,10aS^*)-(+/-)-Hexahydro-7-(1''-methyl-3''-oxobutyl)-7-<3-(phenylmethoxy)propyl>spiroindolizine-2(1H),2'-<1,3>dioxolan>-6(7H)-thione 
• 138489-34-6 (3aα,6α,6aβ,10α,10aβ,10bα)-(+/-)-Octahydro-6a-methyl-10a-<3-(phenylmethoxy)propyl>-1H-3a,10,6-(nitrilomethano)benzazulene-5,8(4H,6H)-dione 
• 138489-33-5 (3aα,4α,7aβ,10aβ,10bα,10cα)-(+/-)-3a,4,5,6,8,9,10,10a,10b,10c-Decahydro-4-hydroxy-1-methyl-10b-<3-(phenylmethoxy)propyl>4,7a-methano-3H,7aH-cyclopenta<4,5>pyrrolo<3,2,1-ij>quinolin-3-one 
• 104115-53-9 (3aα,6α,6aβ,9E,10α,10aβ,10bβ)-(+/-)-9-Ethylideneoctahydro-6a-methyl-10a-<3-(phenylmethoxy)propyl>-1H-3a,10,6-(nitrilomethano)benzazulene-5,8(4H,6H)-dione 
• 138602-84-3 (3aS^*,8aα,12α,12aα,12bβ)-(+/-)-Decahydro-12-methyl-12a-<3-(phenylmethoxy)propyl>spiropyrido<1,2-a>indole-5(4H),2'-<1,3>dioxolan>-10(1H)-one 
• 104115-52-8 (3aS^*,8aα,12aα,12bβ)-(+/-)-2,3,6,7,8a,9,12a,12b-Octahydro-12-methyl-12a-<3-(phenylmethoxy)propyl>spiropyrido<1,2-a>indole-5(4H),2'-<1,3>dioxolan>-10(1H)-one 
• 138602-83-2 (3aS^*,12α,12aα,12bβ)-(+/-)-2,3,6,7,11,12,12a,12b-Octahydro-12-methyl-12a-<3-(phenylmethoxy)propyl>spiropyrido<1,2-a>indole-5(4H),2'-<1,3>dioxolan>-10(1H)-one 
• 138489-37-9 C₃₀H₃₉NO₄ 
• 104115-60-8 C₃₀H₄₁NO₅ 
• 138489-35-7 C₂₉H₃₇NO₅ 
• 138489-36-8 C₂₉H₃₆ClNO₄ 
• 138489-31-3 C₃₄H₅₃NO₄SSi 
• 138489-32-4 C₃₄H₄₃NO₄Se 
• 104115-54-0 (+/-)-3,4-Didehydro-4-<(diethoxyphosphinyl)oxy>-23-(phenylmethoxy)daphnan-14-one 

Relevant academic research and scientific papers

Daphniphyllum Alkaloids. 10. Classical Total Synthesis of Methyl Homodaphniphyllate

Details for the first total synthesis of a Daphniphyllum alkaloid are presented.The synthesis required a total of 15 steps from the known keto acid 4 and followed the course 4 -> 10 -> 11 -> 16 -> 20 -> 24 -> 25 -> 27 -> 29 -> 36 -> 46 -> 47 -> 48 -> 49 -