1041307-62-3Relevant academic research and scientific papers
1,4-hydroiodination of dienyl alcohols with tmsi to form homoallylic alcohols containing a multisubstituted Z -alkene and application to prins cyclization
Xu, Yongjin,Yin, Zhiping,Lin, Xinglong,Gan, Zubao,He, Yanyang,Gao, Lu,Song, Zhenlei
, p. 1846 - 1849 (2015)
A regioselective 1,4-hydroiodination of dienyl alcohols has been developed using trimethylsilyl iodide as Lewis acid and iodide source. A range of homoallylic alcohols containing a multisubstituted Z-alkene was synthesized with good to excellent configurational control. The approach was applied in sequential hydroiodination/Prins cyclization to afford multisubstituted tetrahydropyrans diastereoselectively.
Nucleophilic substitution reaction at an sp2 carbon of vinyl halides with an intramolecular thiol moiety: synthesis of thio-heterocycles
Lei, Mao-Yi,Xiao, Yong-Jun,Liu, Wei-Min,Fukamizu, Koji,Chiba, Shunsuke,Ando, Kaori,Narasaka, Koichi
experimental part, p. 6888 - 6902 (2009/12/06)
This article presents a full account of intramolecular vinylic substitution reactions of bromoalkenes having an acetylthio moiety, which give sulfur-containing heterocycles such as dihydrothiophene, tetrahydrothiopyran, and 2-alkylidenethietane derivative
Nucleophilic substitution at an sp2 carbon of vinyl halides with an intramolecular thiolate moiety: synthesis of 2-alkylidenethietanes
Lei, Mao-Yi,Fukamizu, Koji,Xiao, Yong-Jun,Liu, Wei-Min,Twiddy, Scott,Chiba, Shunsuke,Ando, Kaori,Narasaka, Koichi
, p. 4125 - 4129 (2008/09/21)
Various 2-alkylidenethietanes were synthesized by intramolecular nucleophilic substitution reactions at an sp2 carbon of vinyl halides with thiolate moieties. The reaction pathway of the substitution reactions was confirmed as a very rare Ssub
