104174-53-0

Upstream product

• 1504-72-9 ethyl 3-phenylbut-2-enoate 
• 827-69-0 (E)-4-phenyl-3-penten-2-one 
• 98-86-2 acetophenone 
• 51384-73-7 4-phenyl-3-penten-2-one 
• 536-74-3 phenylacetylene 

Downstream Products

• 1592890-25-9 (E)-(4-methylhepta-1,5-dien-4-yl)benzene 
• 1592890-27-1 (E)-(4-methylhepta-2,6-dien-2-yl)benzene 
• 124006-49-1 (2R,3E)-4-phenyl-3-penten-2-ol 

Relevant academic research and scientific papers

Cobalt-Catalyzed Asymmetric 1,4-Hydroboration of Enones with HBpin

Herein, a series of new 8-OIQ cobalt complexes were synthesized and used for cobalt-catalyzed chemo- and enantioselective 1,4-hydroboration of enones with HBpin to access chiral β,β-disubstituted ketones with good to excellent chemo- and enantioselectivties. This protocol is operationally simple and shows a broad substrate scope.

Catalytic stereospecific allyl-allyl cross-coupling of internal allyl electrophiles with allylB(pin)

Application of internal electrophiles in catalytic stereospecific allyl-allyl cross-coupling enable the rapid construction of multisubstituted 1,5-dienes, including those with all carbon quaternary centers. Compounds with minimal steric differentiation ca