1041860-29-0Relevant articles and documents
Versatile coordination of N-(diisopropoxyphosphoryl)-p-bromothiobenzamide towards Zn(II) and Cd(II)
Safin, Damir A.,Klein, Axel,Babashkina, Maria G.,N?th, Heinrich,Krivolapov, Dmitriy B.,Litvinov, Igor A.,Kozlowski, Henryk
, p. 1504 - 1510 (2009)
Reaction of the potassium salt of N-(diisopropoxyphosphoryl)-p-bromothiobenzamide p-BrC6H4C(S)NHP(O)(OiPr)2 (HL) with Zn(II) and Cd(II) cations in aqueous EtOH leads to the three different complexes: [Zn(L-O,S)2
Studies on zinc(II) complexes with N-thioacylamidophosphates: X-ray crystal structure of the [Zn(RC(S)NP(O)(OiPr)2)2] (R = NH2, tBuNH, c-C6H11NH)
Safin, Damir A.,Sokolov, Felix D.,N?th, Heinrich,Babashkina, Maria G.,Gimadiev, Timur R.,Galezowska, Joanna,Kozlowski, Henryk
, p. 2022 - 2028 (2009/03/11)
The photoluminescent properties of 17 zinc(II) chelates [Zn(RC(S)NP(O)(OiPr)2-O,S)2] (R = Ph (1a), PhNH (1b), p-BrPh (1c), p-MeOC6H4NH (1d), p-BrC6H4NH (1e), NH2 (1f), iPrNH (1g), tBuNH (1h), Et2N (1i), c-C5H10N (1j), c-OC4H8N (1k), c-C6H11NH (1l), aminobenzo-15-crown-5 (1m)) and [Zn(B)(RC(S)NP(O)(OiPr)2-O,S)2] (R = Ph, B = 2,2′-bipyridine (2a); R = Ph, B = 1,10-phenanthroline (2b); R = PhNH, B = 2,2′-bipyridine (2c); R = PhNH, B = 1,10-phenanthroline (2d)), are reported. Colorless and air/moisture stable chelate complexes of divalent zinc show blue emission in the solid state when excited with UV light. Complexes 1f, 1h, 1l were investigated by single crystal X-ray diffraction. The zinc(II) atom in complexes 1f, 1h, 1l is in a distorted tetrahedral O2S2 environment formed by the C{double bond, long}S sulphur atoms and the P{double bond, long}O oxygen atoms of two deprotonated ligands.
