1042302-30-6

Basic information

• Product Name: 4,12-diphenyl-2,3,11-trioxatricyclo[4.4.3.0(1,6)]tridec-12-en-7-one
• CAS NO: 1042302-30-6
• Molecular Weight: 348.398
• Mol File: 1042302-30-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4,12-diphenyl-2,3,11-trioxatricyclo[4.4.3.0(1,6)]tridec-12-en-7-one(CAS DataBase Reference)
• NIST Chemistry Reference: 4,12-diphenyl-2,3,11-trioxatricyclo[4.4.3.0(1,6)]tridec-12-en-7-one(1042302-30-6)
• EPA Substance Registry System: 4,12-diphenyl-2,3,11-trioxatricyclo[4.4.3.0(1,6)]tridec-12-en-7-one(1042302-30-6)

Safety Data

• Hazardous Substances Data: 1042302-30-6(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 14073-26-8 2-(2-oxo-2-phenylethyl)cyclohexane-1,3-dione 

Relevant articles and documents

Facile endoperoxypropellane synthesis by manganese(III) acetate-mediated aerobic oxidation

Manganese(III)-catalyzed aerobic oxidation of combinations of 3-(2-oxoethyl)piperidine-2,4-diones and 1,1-diarylethenes at room temperature produced structurally interesting trioxaaza[ 4.4.3]propellanes in good yields. Similar reactions using 2-(2-oxoethyl)cyclohexane-1,3-diones also produced the corresponding endoperoxy[4.4.3]propellanes. On the other hand, 3-oxopropyl-substituted cycloalkane-1,3-diones did not give the desired propellanes, 1,2-dioxabicyclic propellane precursors were formed instead in excellent yields. The precursors could be converted into the corresponding propellanes in the presence of a Lewis acid. The mechanism for the formation of the propellanes is also described. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.