104259-90-7

Usage

Molecular weight

127.14 g/mol

Properties

Cyclic enamine
White solid
Melting point: 48-51°C
Boiling point: 110-112°C at 5 mmHg

Uses

Building block in organic synthesis
Utilized in the pharmaceutical industry for drug synthesis
Intermediate in the production of organic compounds
Academic research purposes

Upstream product

• 121569-43-5 (-)-5-methoxy-2-methyl-2-azabicyclo<2.2.0>hex-5-en-3-one 
• 104259-89-4 5-benzyloxy-2-methyl-2-azabicyclo<2.2.0>hex-5-en-3-one 
• 53937-03-4 N‐methyl‐4‐benzyloxy‐2‐pyridone 
• 53937-02-3 4-(benzyloxy)pyridin-2(1H)-one 

Downstream Products

• 97222-37-2 4-<(benzylthio)carbonylmethyl>-1-methylazetidin-2-one 
• 97222-36-1 4-benzyloxycarbonylmethyl-1-methylazetidin-2-one 

Relevant academic research and scientific papers

X-Ray Structural Study of 1:1 Complex of 4-Methoxy-1-methylpyridone and (R,R)-(-)-1,6-Bis(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol the Irradiation of which gives Optically Pure β-Lactam

A 1:1 complex of 4-methoxy-1-methylpyridone and (R,R)-(-)-1,6-bis(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol, on irradiation, gives a pure β-lactam.The mechanism for this photoconversion has been studied by means of an X-ray crystallographic analysis of the complex.

Cycloadditions in Syntheses. Part 28. 2-Azabicyclohexane-3,5-dione and its Derivatives: Synthesis and Transformation to Azetidin-2-ones

2-Azabicyclohexane-3,5-dione has been synthesized via photopyridone formation from 4-(dimethyl-t-butylsiloxy)- or 4-alkoxy-2-pyridones followed by mild acid hydrolysis.The title compound and its derivatives react with a variety of nucleophiles (ROH