104261-13-4Relevant academic research and scientific papers
EASY ENTRY TO TRICYCLO(7,3,1,01-6)TRIDECANE SYSTEM
Houbrechts, Yvette,Laszlo, Pierre,Pennetreau, Pascal
, p. 705 - 706 (1986)
Michael addition of two equivalents of methylvinylketone to dimedone, followed by acid-catalyzed cyclization give in 64percent overall yield a strained tricyclic molecule with a spiro ring junction.
The remarkable catalytic activity of ultra-small free-CeO2 nanoparticles in selective carbon-carbon bond formation reactions in water at room temperature
Banerjee, Subhash
supporting information, p. 5350 - 5353 (2015/07/07)
A simple and efficient protocol for selective bis-Michael addition and mono-allylation of active methylene compounds has been demonstrated using ultra-small (size ～5 nm) uncapped cerium oxide nanoparticles (free-CeO2 NPs) as a reusable catalyst in water at room temperature. The free-CeO2 NPs were characterized by powder XRD, TEM and XPS studies. Free-CeO2 NPs efficiently catalyzed both the reactions and produced good to excellent yields of products.
Remarkable catalytic activity of silica nanoparticle in the bis-Michael addition of active methylene compounds to conjugated alkenes
Banerjee, Subhash,Santra, Swadeshmukul
experimental part, p. 2037 - 2040 (2009/09/05)
We have demonstrated the remarkable catalytic activity of silica nanoparticles (NPs) in the unusual bis-Michael addition of active methylene compounds to conjugated alkenes at room temperature. The catalyst silica NPs were reused up to seven runs without appreciable loss of catalytic activity.
