104264-93-9

Upstream product

• 104197-82-2 (1R,2S,5R)-2-tert-butyl-5-methylcyclohexyl (nitrooxy)acetate 
• 75419-02-2 (1R,2S,5R)-2-dimethylethyl-5-methyl-cyclohexan-1-ol 
• 56782-80-0 (2S,5R)-2-(tert-butyl)-5-methylcyclohexan-1-one 
• 89-82-7 pulegone 
• 104197-96-8 (1R,2S,5R)-2-tert-butyl-5-methylcyclohexyl bromoacetate 

Downstream Products

• 104264-95-1 (1R,2S,5R)-2-tert-butyl-5-methylcyclohexyl (2R)-2-hydroxy-4(E)-octenoate 
• 104197-83-3 (1R,2S,5R)-2-tert-butyl-5-methylcyclohexyl (2S)-2-hydroxy-4(E)-octenoate 
• 153809-46-2 (S)-[4-(tert-Butyl-dimethyl-silanyloxy)-phenyl]-hydroxy-acetic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 

Relevant academic research and scientific papers

Auxiliary Structure and Asymmetric Induction in the Ene Reactions of Chiral Glyoxylates

A variety of chiral auxiliares (1a-13a) were prepared and tested for levels of asymmetric induction control in the ene reaction of chiral glyoxylates.Structural features required for high levels of control were defined by systematic modification of the auxiliary, providing systems with induction levels that ranged from 1.2 to 1 to better than 99.9 to 0.1.