1042740-75-9Relevant academic research and scientific papers
Enantioselective rhodium-catalyzed addition of arylboronic acids to α-ketoesters
Duan, Hai-Feng,Xie, Jian-Hua,Qiao, Xiang-Chen,Wang, Li-Xin,Zhou, Qi-Lin
supporting information; scheme or table, p. 4351 - 4353 (2009/02/08)
(Chemical Figure Presented) Rhodium catalysis: The first example of a catalytic asymmetric addition of arylboronic acids to α-ketoesters was realized by using a chiral RhI-spirophosphite ligand complex in aqueous solvent to provide tertiary α-hydroxyesters in good yields with high enantioselectivities (see scheme; DCE = 1,2-dichloroethane).
