104307-65-5Relevant academic research and scientific papers
STEREOCONTROLLED SYNTHESIS OF (R*R*)- AND (R*S*)-5-HYDROXY-2-METHYLHEXANOIC ACID LACTONES. PHEROMONE OF THE CARPENTER BEE VIA PALLADIUM-CATALYZED REACTIONS
Baeckvall, J. E.,Bystroem, S. E.,Nystroem, J. E.
, p. 5761 - 5764 (2007/10/02)
(E,Z)-2,4-Hexadiene was transformed to the lactone cis-1(>93percent cis)(pheromone of the carpenter bee) in a stereospecific reaction sequence via a Pd-catalyzed 1,4-acetoxychlorination.The same reaction sequence applied to (E,E)-2,4-hexadiene afforded th
