104330-53-2

Upstream product

• 64-17-5 ethanol 
• 78987-20-9 3-<(2-methylphenyl)amino>-3-oxopropanoic acid 
• 95-53-4 o-toluidine 
• 105-53-3 diethyl malonate 
• 875778-80-6 2-[bis(benzylthio)methylene]-3-oxo-N-o-tolylbutanamide 
• 1071-46-1 hydrogen ethyl malonate 
• 159754-84-4 N-o-tolyl-3,3,3-trifluoro-2,2-dihydroxypropionamide 
• 140428-80-4 anhydride of malonic acid monoethyl ester 

Downstream Products

• 78987-20-9 3-<(2-methylphenyl)amino>-3-oxopropanoic acid 
• 1430745-30-4 ethyl 5-acetyl-6-hydroxy-6-methyl-1-(2-methylphenyl)-2-oxo-4-phenylpiperidine-3-carboxylate 
• 1430745-34-8 ethyl 5-acetyl-6-hydroxy-4-(4-dimethylaminophenyl)-6-methyl-1-(2-methylphenyl)-2-oxopiperidine-3-carboxylate 
• 10378-79-7 N₁,N₃-di-o-tolylmalonamide 
• 105-53-3 diethyl malonate 
• 70793-50-9 Malonsaeure-o-toluidid-hydrazid 

Relevant academic research and scientific papers

Diazo Esters Addition to Trifluoropyruvamides: New Access to Highly Functionalized Trifluoromethyl Epoxides and Diazo Compounds

Trifluoropyruvamides in their hydrated form readily react with diazo esters affording new trifluoromethyl epoxides. Activating the pyruvamide with trifluoroacetic anhydride leads to a complete change in selectivity with the formation of a new diazo compound.

An efficient and odorless synthesis of thioethers using 2-[Bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as thiol equivalents

Using 2-[bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides 1 as odorless thiol equivalents, an efficient and odorless synthesis of thioethers has been developed. Promoted by NaOH in EtOH, the cleavage of 1 commences to generate thiolate anions, and the generated thiolate anions then react with halides to give various thioethers in good yield. It is noteworthy that only a very faint odor of thiols can be perceived during both the reaction and the workup. Using 2-[bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as odorless thiol equivalents, an efficient and odorless synthesis of thioethers has been developed. Promoted by NaOH in EtOH, the cleavage of 2-[bis(alkylthio)methylene] -3-oxo-N-o-tolylbutanamides commences to generate thiolate anions, and the generated thiolate anions then react with halides to give various thioethers in good yield. Copyright

Ethyl Esters of Malonanilic Acids. Synthesis and Pyrolysis

The pyrolysis under 170-220 deg C or boiling in DMF of malonanilic acids ethyl esters (2) is accompanied by formation of malonic acids symmetric dianilides (7) with high yields.A possible mechanism for this transformation has been suggested.

1,2-Dithiol-3-ylideneammonium derivatives, compositions and use

New compounds of the formula: STR1 wherein X? is an anion, R is (C1-7) alkyl [unsubstituted or substituted by hydroxy, carboxy, alkoxycarbonyl, cyano, dialkylamino, alkylcarbonyl, or benzoyl which is unsubstituted or substituted by o