104367-36-4Relevant academic research and scientific papers
ORIGINAL REACTIONS OF α,α-DITHIO ARYL ALKANES WITH BUTYLLITHIUMS
Krief, Alain,Kenda, Benoit,Barbeaux, Philippe
, p. 2509 - 2512 (2007/10/02)
Thioacetals derived from aromatic ketones react with butyllithiums already at -78 deg C and produce via a reductive process the corresponding α-thiobenzyllithiums in high yields.The same reaction also takes place selectively, under suitable conditions, wi
THE REDUCTIVE LITHIATION OF THIOACETALS, α,α-BIS(TRIMETHYLSILYL)-ALKYL SULFIDES, AND 2-ALKYL-2-ETHYLTHIOALKANENITRILES USING TRIBUTYLSTANNYLLITHIUM
Takeda, Takeshi,Ando, Kazuo,Mamada, Akira,Fujiwara, Tooru
, p. 1149 - 1152 (2007/10/02)
The reaction of thioacetals of phenyl ketones, α,α-bis(trimethylsilyl)alkyl sulfides, and 2-alkyl-2-ethylthioalkanenitriles with tributhylstannyllithium gave the corresponding α-anions of sulfides, α,α-bis(trimethylsilyl)alkane, and nitriles, respectively.
