104367-65-9Relevant academic research and scientific papers
Activation of C-H bonds via the merger of photoredox and organocatalysis: A coupling of benzylic ethers with schiff bases
Hager, Dominik,Macmillan, David W. C.
, p. 16986 - 16989 (2014)
The photoredox-mediated coupling of benzylic ethers with Schiff bases has been accomplished. Direct benzylic C-H activation by a combination of a thiol catalyst with an iridium photocatalyst and subsequent radical-radical coupling with secondary aldimines
ANION RADICAL-INDUCED DESILYLATION OF ORGANOSILANE. REACTIONS OF BENZYLSILANES WITH ALDEHYDES AND RELATED COMPOUNDS IN THE PRESENCE OF BUTYLLITHIUM OR LITHIUM METAL
Kanemasa, Shuji,Tanaka, Junji,Nagahama, Hideki,Tsuge, Otohiko
, p. 1223 - 1226 (2007/10/02)
By the action of butyllithium or lithium metal in such polar aprotic solvent as DMF or HMPA in the presence of aldehydes or related compounds, some benzylsilanes suffer from anion radicalinduced desilylation forming benzyl carbanions which add to the aldehydes and related compounds.
