104418-40-8

Basic information

• Product Name: (S)-(+)-2-METHYLBUTYL METHANESULFONATE
• Synonyms: (S)-(+)-2-METHYLBUTYL METHANESULFONATE;(S)-(+)-2-METHYLBUTYL METHANESULFONATE 99%;(+)-Methanesulfonic acid (S)-2-methylbutyl ester;[S,(+)]-2-Methyl-1-butanol methanesulfonate
• CAS NO: 104418-40-8
• Molecular Formula: C₆H₁₄O₃S
• Molecular Weight: 166.24
• Product Categories: Sulfonates/Sulfinates;Chiral Building Blocks;Organic Building Blocks
• Mol File: 104418-40-8.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 253.7°Cat760mmHg
• Flash Point: >230 °F
• Appearance: /
• Density: 1.08 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0287mmHg at 25°C
• Refractive Index: n20/D 1.432(lit.)
• CAS DataBase Reference: (S)-(+)-2-METHYLBUTYL METHANESULFONATE(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(+)-2-METHYLBUTYL METHANESULFONATE(104418-40-8)
• EPA Substance Registry System: (S)-(+)-2-METHYLBUTYL METHANESULFONATE(104418-40-8)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 104418-40-8(Hazardous Substances Data)

Usage

General Description

(S)-(+)-2-methylbutyl methanesulfonate, also known as (S)-methyl 2-methylbutyl sulfonate, is a chemical compound with the molecular formula C6H14O3S. It is a chiral molecule, meaning it has a non-superimposable mirror image, and is commonly used as an intermediate in organic synthesis. This chemical is often utilized as a reagent for the synthesis of various pharmaceuticals and fine chemicals due to its ability to act as a mild and effective leaving group. It is also used in the production of fragrances and flavors, as well as in the manufacturing of other organic compounds. Due to its reactivity and utility in organic synthesis, (S)-(+)-2-methylbutyl methanesulfonate is a valuable and versatile compound in the field of chemical research and manufacturing.

InChI:InChI=1/C6H14O3S/c1-4-6(2)5-9-10(3,7)8/h6H,4-5H2,1-3H3/t6-/m0/s1

Upstream product

• 1565-80-6 (2S)-2-methyl-1-butanol 
• 124-63-0 methanesulfonyl chloride 
• 1730-91-2 (S)-2-Methylbutyric acid 

Downstream Products

• 53531-21-8 (+)-<(S)-2-methylbutyl>diphenylphosphine 
• 141032-65-7 (S)-(N-methyl-N-2-methylbutyl)aniline 
• 193340-33-9 (S)-N-(2-methylbutyl)-N-phenylamine 
• 29394-58-9 (S)-1-iodo-2-methyl-butane 
• 853993-12-1 (2S)-2-methylbutyl 2,5-dihydroxybenzoate 
• 1160934-37-1 C₁₈H₂₄Cl₂O₄ 
• 1454710-06-5 C₅₈H₈₈N₆O₁₀ 
• 1454710-10-1 C₄₈H₇₂N₆O₆ 
• 1454709-98-8 C₅₃H₇₇N₃O₁₁ 
• 1454710-02-1 C₅₁H₇₃N₃O₁₁ 
• 1454709-94-4 4,6-bis((S)-2-methylbutoxy)isophthalic acid 
• 1454709-91-1 5-(methoxycarbonyl)-2,4-bis((S)-2-methylbutoxy)benzoic acid 
• 1454709-88-6 dimethyl 4,6-bis((S)-2-methylbutoxy)isophthalate 
• 71777-35-0 (+)-(S)-10-methyldodecyl acetate 

Relevant articles and documents

Enantioselective cyclopropane syntheses using the chiral carbene complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe=CHCH 3+. A mechanistic analysis of the carbene transfer reaction

Enantiomerically pure or enriched iron-carbene complexes of the type C5H5(CO)(PR3)Fe=CHCH3+ have been prepared by three routes: (a) Diastereomeric acyl complexes C5H5(CO)(PPhsub

Additive components for liquid crystalline materials

The present invention relates to mesogenic, cross-linkable mixtures comprising (i) a cross-linkable liquid crystalline host compound comprising at least one cross-linkable liquid crystalline compound, and (ii) at least one chiral or achiral rod shaped additive component, wherein said additive component has a rigid core and comprises at least two fused or linked, optionally substituted, non-aromatic, aromatic, carbocyclic or heterocyclic groups, and also comprises at least one optionally substituted alkyl residue, and at least one polymerizable group and wherein the additive component has a transition temperature to the isotropic state of 40° C. or lower. The invention also relates to the novel chiral or achiral rod-shaped additive compounds used for the preparation of these mixtures, to mixtures according to the invention in form of an elastomer, polymer gel, polymer network or polymer film, to polymer networks and liquid crystalline polymer films prepared from these mixtures and to optical or electrooptical components comprising polymer networks and liquid crystalline polymer films prepared from such mixtures. Further, the invention relates to the use of the chiral or achiral rod shaped compounds as components of a cross-linkable liquid crystalline mixture in the production of orientated liquid crystalline polymers, to liquid crystalline mixtures comprising these compounds, to liquid crystalline polymers and liquid crystalline polymer networks prepared from such liquid crystalline mixtures, and to liquid crystalline devices comprising these compounds.

Scavenger assisted combinatorial process for preparing libraries of tertiary amine compounds

This invention relates to a novel solution phase process for the preparation of tertiary amine combinatorial libraries. These libraries have utility for drug discovery and are used to form wellplate components of novel assay kits.