104431-32-5Relevant academic research and scientific papers
ARYLATION OF FURAN COMPOUNDS BY ARENEDIAZONIUM SALTS
Obushak, N. D.,Ganushchak, N. I.,Lesyuk, A. I.,Dzikovskaya, L. M.,Kisilitsa, P. P.
, p. 748 - 753 (2007/10/02)
3-(5-Aryl-2-furyl)acrylic acids were obtained by the reaction of 5-arylfurfurals with malonic acid.They were arylated by diazonium salts with decarboxylation and the formation of 5-aryl-2-styrylfurans.The latter were also obtained by the interaction of furylacrolein with diazonium salts.This reaction also gave 3-(5-aryl-2-furyl)acroleins and the corresponding arylfurylacrylic acids, which were arylated again with the release of CO2 and the formation of 5-aryl-2-styrylfurans. 3-(5-Aryl-2-furyl)acroleins were also synthesized by the condensation of 5-arylfurfurals with acetaldehyde under phase-transfer conditions.The s-trans configuration of the furan ring and the exocyclic double bond were established in the obtained compounds by the PMR method.
NEW SYNTHESIS OF 2-(4-NITROPHENYL)-1-(5-NITRO-2-FURYL)ETHYLENE AND 2-(4-ETHOXYCARBONYLPHENYL)-1-(5-NITRO-2-FURYL)ETHYLENE
Hrabovsky, Jan,Kovac, Jaroslav
, p. 3130 - 3133 (2007/10/02)
(E)-2-Ar-1-(5-nitro-2-furyl)ethylenes (were Ar is O2N-C6H4- or H5C2OOC-C6H4-) were prepared by reaction of aryldiazonium salts with 3-(5-nitro-2-furyl)-2-propenoic acid or 2-bromo-1-(5-nitro-2-furyl)ethylene.Photochemical modification of Meerwein reaction
