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4-Nitrobenzenediazonium chloride, with the molecular formula C6H4N3Cl and a molecular weight of 158.57 g/mol, is an organic diazonium salt. It is a yellow crystalline solid that is sensitive to light and moisture. Due to its potential explosive nature and high toxicity, it requires careful handling in a well-ventilated area with appropriate personal protective equipment.

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  • 100-05-0 Structure
  • Basic information

    1. Product Name: 4-nitrobenzenediazonium chloride
    2. Synonyms: 4-nitrobenzenediazonium chloride;4-Nitro-1-benzenediazonium·chloride
    3. CAS NO:100-05-0
    4. Molecular Formula: C6H4ClN3O2
    5. Molecular Weight: 185.56786
    6. EINECS: 202-814-3
    7. Product Categories: N/A
    8. Mol File: 100-05-0.mol
    9. Article Data: 60
  • Chemical Properties

    1. Melting Point: 243-243.5 °C
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 4-nitrobenzenediazonium chloride(CAS DataBase Reference)
    10. NIST Chemistry Reference: 4-nitrobenzenediazonium chloride(100-05-0)
    11. EPA Substance Registry System: 4-nitrobenzenediazonium chloride(100-05-0)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 100-05-0(Hazardous Substances Data)

100-05-0 Usage

Uses

Used in Organic Synthesis:
4-Nitrobenzenediazonium chloride is used as a diazo transfer agent for the preparation of various organic compounds. It plays a crucial role in the synthesis of azo dyes and pigments, which are widely used in the textile, paint, and printing industries.
Used in Chemical Research:
In the field of chemical research, 4-Nitrobenzenediazonium chloride is utilized as a reagent for studying the properties and reactions of diazonium salts. It helps researchers understand the mechanisms of diazo coupling reactions and develop new synthetic methods.
Used in Analytical Chemistry:
4-Nitrobenzenediazonium chloride is employed as a derivatizing agent in analytical chemistry. It is used to convert amines into diazonium salts, which can then be analyzed using various analytical techniques such as spectrophotometry and chromatography.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 4-Nitrobenzenediazonium chloride is used as an intermediate in the synthesis of certain drugs and pharmaceutical compounds. Its ability to transfer diazo groups makes it a valuable component in the development of new medications.
Used in Dye and Pigment Manufacturing:
4-Nitrobenzenediazonium chloride is used as a key ingredient in the production of azo dyes and pigments. These dyes and pigments are essential for coloring various materials, including textiles, plastics, and paints, and are widely used in the manufacturing industry.

Check Digit Verification of cas no

The CAS Registry Mumber 100-05-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 0 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 100-05:
(5*1)+(4*0)+(3*0)+(2*0)+(1*5)=10
10 % 10 = 0
So 100-05-0 is a valid CAS Registry Number.
InChI:InChI=1/C6H4N3O2/c7-8-5-1-3-6(4-2-5)9(10)11/h1-4H/q+1

100-05-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-Nitrobenzenediazonium chloride

1.2 Other means of identification

Product number -
Other names p-nitrobenzene diazonium chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:100-05-0 SDS

100-05-0Relevant articles and documents

Synthesis and chemical reactivity of 3-oxo-2-arylhydrazono-propanenitriles

Abdallah, Sanaa O.,Metwally, Nadia H.,Anwar, Hany F.,Elnagdi, Mohamed H.

, p. 781 - 786 (2005)

2-Formyl-2-arylhydrazonoethanenitriles 6b-d where prepared via reacting enaminonitrile 2b,c with aromatic diazonium salts. These reacted with phenylhydrazine to yield bis hydrazones that were converted to arylazopyrazoles via a novel Vilsmeier-Haack reaction type. Reaction of 6c with hydroxylamine afforded oxime that could be successfully cyclised into arylazoisoxazole. Reaction of 6c with hydrazine hydrate to yield arylazoaminopyrazole that proved to be excellent precursors for synthesis functional substituted pyrazolopyrimidines.

Synthesis and liquid crystalline properties of a disc-shaped molecule with azobenzene at the periphery

Rahman, Md. Lutfor,Tschierske, Carsten,Yusoff, Mashitah,Silong, Sidik

, p. 2303 - 2306 (2005)

A triphenylene-based novel liquid crystal was synthesised whose peripheral cores are six rod-like azobenzene moieties linked through alkyl chains. A disc-shaped molecule 2,3,6,7,10,11-hexakis-[{4-(4-nitrophenylazo)phenoxy} hexyloxy]triphenylene was prepar

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, p. 259 - 262 (2015)

Under the guidance of the finding that the tyrosine residues in proteins could undergo three-component Mannich-type reactions with formaldehyde and electron-rich aniline-containing compounds, which forms covalent bonding connections between the protein of

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Althagafi, Ismail,Morad, Moataz,Al-dawood, Aisha Y.,Yarkandy, Naema,Katouah, Hanadi A.,Hossan, Aisha S.,Khedr, Abdalla M.,El-Metwaly, Nashwa M.,Ibraheem, Farag

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Novel Zn(II)–benzohydrazide complexes have been synthesized using Zn(NO3)2·6H2O salt. All new synthesises were investigated by available analytical and spectral tools to demonstrate their formulae. Binuclear complexes were

Synthesis and characterization of new pyrazole-based thiazoles

Abdelhamid, Abdou O.,Gomha, Sobhi M.

, p. 1409 - 1414 (2017)

A series of new 5-(heteroaryldiazenyl)thiazole incorporating pyrazole moiety have been synthesized through coupling of the thiazole with the appropriate heteroaryldiazonium salts. The newly synthesized compounds were characterized by elemental analysis, s

Synthesis and crystal structure of 1-methyl-3-(4-nitrophenyl)-1,2,3 triazolium perchlorate

Doreswamy,Mahendra,Sridhar,Prasad, J. Shashidhara,Mantelingu,Basappa,Rangappa

, p. 67 - 75 (2003)

The isolation of stable carbenes of the Arduengo (1a) and Wanzlick (2a) type has prompted us to look for stable nitrenium ions of the related structural type 1-melhyl-3-(4-nitrophenyl)-1,2,3 triazolium perchlorate (6). The title compound (C9 H

N-acyl triazenes as tunable and selective chemodosimeters toward cyanide ion

Chung, Yunmi,Lee, Hanna,Kyo, Han Ahn

, p. 9470 - 9474 (2006)

(Figure Presented) A novel type of chemodosimeters has been developed on the basis of a displacement reaction. N-Acyl-triazenes are found to be highly selective and tunable chemodosimeters toward cyanide. When N-acetyl-triazene 1a was titrated with variou

Fluoride-responsive organogel containing azobenzyl and cholesterol units

Geng, Lijun,Feng, Guoliang,Wang, Shiguang,Yu, Xudong,Xu, Zhice,Zhen, Xiaoli,Wang, Tao

, p. 24 - 28 (2015)

In this paper, two new cholesterol-based compounds O1 and O2 were designed and synthesized. The compound O2 could selectively gel in 1,4-dioxane with porous ribbon structure. The aggregation mode of O2 molecules were characterized by SEM, IR, UV-vis and X

Experimental and theoretical studies of azo derivatives in terms of different donors, acceptors and position isomerism: Synthesis, characterization and a combined electronic absorption, electrochemical and DFT study

Haridas, Karickal R.,Janardanan, Deepa,Mohan A, Keerthi,Purushothaman, Aiswarya

, (2021/10/12)

Eight azo derivatives with two donor groups- diphenylamine and N,N-dimethylphenyl, and four acceptor groups - 3-nitrophenyl, 4-nitrophenyl, 4-phenylcarboxylic acid, and 3-phenylcarboxylic acid, were synthesized and characterized using 1H-NMR an

A comprehensive spectroscopic, solvatochromic and photochemical analysis of 5-hydroxyquinoline and 8-hydroxyquinoline mono-azo dyes

Coelho, Paulo J.,Lup, Andrew Ng Kay,Mahon, Peter J.,Pesyan, Nader Noroozi,Ramezanitaghartapeh, Mohammad,Raposo, M. Manuela M.,Rashidnejad, Hamid,Soltani, Alireza

, (2020/10/06)

A series of novel substituted-azo dyes 8-(aryldiazenyl)quinolin-5-ol (5a-i) were synthesized by the coupling reaction of 5-hydroxyquinoline with diazotized aniline derivatives in the presence of NaNO2 in HCl/H2O mixture. The study of

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