104464-22-4

Upstream product

• 104464-05-3 (1R,4S,6S)-4-Hydroxy-6-((S)-2-methyl-1-phenyl-propoxy)-1-(toluene-4-sulfonyl)-cyclohex-2-enecarboxylic acid methyl ester 
• 104464-08-6 (3R,4S,6S)-3,4-Dihydroxy-6-((S)-2-methyl-1-phenyl-propoxy)-cyclohex-1-enecarboxylic acid methyl ester 
• 104464-04-2 (1S,4R,8S)-8-((S)-2-Methyl-1-phenyl-propoxy)-4-(toluene-4-sulfonyl)-2-oxa-bicyclo[2.2.2]oct-5-en-3-one 
• 104464-09-7 (3R,4S,6S)-3,4-Diacetoxy-6-((S)-2-methyl-1-phenyl-propoxy)-cyclohex-1-enecarboxylic acid methyl ester 

Relevant academic research and scientific papers

Highly Stereocontrolled Synyhesis of Some Trioxygenated Cyclohexenes: An Asymmetric Total Synthesis of (-)-Methyl Triacetyl-4-epishikimate

Polyfunctional bicyclic lactone (-)-1 serves as a chiron for preparation of 3,4,6-trioxygenated cyclohexene (-)-5a in 56.6percent overall yield and for synthesis of (-)-methyl triacetyl-4-epishikimate, (-)-12, in 14 steps and in 23.4percent overall yield.