1044748-06-2Relevant academic research and scientific papers
Biomimetic synthesis of resorcylate natural products utilizing late stage aromatization: Concise total syntheses of the marine antifungal agents 15G256ι and 15G256β
Navarro, Ismael,Basset, Jean-Francois,Hebbe, Severine,Major, Sarah M.,Werner, Thomas,Howsham, Catherine,Braeckow, Jan,Barrett, Anthony G. M.
, p. 10293 - 10298 (2008)
Diketo-1,3-dioxin-2-ones underwent retro-Diels-Alder reaction on heating in toluene at 110°C to generate α,γ,ε-triketo-ketenes. These were trapped with alcohols to provide 2,4,6-triketocarboxylates, which were smoothly aromatized by sequential reaction wi
